Aggregation of dinuclear {Fe2hpdta} units to form polynuclear oxy/hydroxy-bridged Fe(iii) coordination complexes
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منابع مشابه
Aggregation of dinuclear {Fe2hpdta} units to form polynuclear oxy/hydroxy-bridged Fe(III) coordination complexes.
An approach for the preparation of oxy/hydroxy briged Fe(III) clusters that takes advantage of hydrolytic condensations of well defined {Fe(2)hpdta(H(2)O)(4)} building units is presented. Co-ligands such as tripodal H(3)tea or bidentate organic bases such as ethylenediamine (enH(2)) can be used to complete the coordination spheres of the Fe(III) centres and stabilise unsymmetrical iron-oxo clus...
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ژورنال
عنوان ژورنال: Dalton Transactions
سال: 2010
ISSN: 1477-9226,1477-9234
DOI: 10.1039/c0dt00655f